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Over
the past years of experience, Lime Industries
have collected numerous questions from customers
and lime users and compiled them in our FAQ page.
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Q:
What is lime? What are the differences between quicklime
and hydrated lime, high calcium lime and dolomitic lime?
A: Lime is a generic term, but by strict definition it
embraces only the manufactured forms of lime—quicklime and
hydrated lime. It does not include limestone, which is the
feedstock for lime manufacturing (click here for a short description
on how lime is produced).
Quicklime,
the product of calcination of limestone, consists of the
oxides of calcium and magnesium, and in the United States
it is available in three forms:
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High calcium quicklime--derived
from limestone containing 0 to 5 percent magnesium carbonate.
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Magnesian quicklime--derived
from limestone containing 5 to 35 percent magnesium
carbonate. |
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| Dolomitic quicklime--derived
from limestone containing 35 to 46 percent magnesium
carbonate. |
Hydrated
lime is a dry powder manufactured by treating quicklime
with sufficient water to satisfy its chemical affinity for
water, thereby converting the oxides to hydroxides. Depending
upon the type of quicklime used and the hydrating conditions
employed, the amount of water in chemical combination varies,
as follows:
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High calcium hydrated lime--high
calcium quicklime produces a hydrated lime containing
generally 72 to 74 percent calcium oxide and 23 to 24
percent chemically combined water. |
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Dolomitic hydrated lime
(normal)--under atmospheric hydrating conditions only
the calcium oxide fraction of dolomitic quicklime hydrates,
producing a hydrated lime of the following chemical
composition: 46 to 48 percent calcium oxide, 33 to 34
percent magnesium oxide, and 15 to 17 percent chemically
combined water. |
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| Dolomitic hydrated lime
(pressure)--this lime is produced from dolomitic quicklime
under pressure, which results in hydrating all of the
magnesium oxide as well as all of the calcium oxide,
producing the following chemical composition: 40 to
42 percent calcium oxide, 29 to 30 percent magnesium
oxide, and 25 to 27 percent chemically combined water.
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Q:
What about physical specifications for lime?
A: Hydrated lime is available only as a fine powder or
a slurry. Normal grades of hydrated lime suitable for most
chemical purposes will have 85 percent or more passing a 200-mesh
sieve, while for special applications hydrated lime may be
obtained as fine as 99.5 percent passing a 325-mesh sieve.
Quicklime,
however, is commercially available in a number of sizes
(the following definitions are derived from ASTM Standard
C51):
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Large lump lime--a maximum
of eight inches in diameter. |
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Crushed or pebble lime--ranging
from about ¼ to 2 ½ inches. |
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| Ground lime-- ¼
inches and smaller. |
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| Pulverized
lime--a typical size is substantially all passing a
No. 20 sieve. |
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| Pelletized lime--one inch
sized pellets or briquettes, molded from fines. |
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Q:
What are the differences between Type N, NA, S, & SA hydrated
lime used for mortar and other building applications?
A: Hydrated limes used in building applications are divided
into four types, as described in ASTM Standard Specification
C 207 (Hydrated Lime for Masonry Purposes):
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Type N normal hydrated
lime |
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Type NA normal air-entraining
hydrated lime |
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| Type S special hydrated
lime |
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| Type SA special
air-entraining hydrated lime
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Q:
Is aglime the same as lime?
A: The term agricultural lime, or "aglime," usually refers
to limestone. Limestone (calcium carbonate) is not the same
as hydrated lime (calcium hydroxide).
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Q:
Do you have a listing of the specifications for lime in
various industrial uses?
A: There is an ASTM standard, C911, for lime used in chemical
(and industrial) uses. Uses addressed include water softening,
other water treatment, hypochlorite bleach, silica brick,
calcium silicate products, industrial waste treatment, sulfite
pulp, and carbide. The standard can be purchased directly
from ASTM at www.astm.org.
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Q:
What procedures should I use to test lime?
A: ASTM has Standard Methods for testing chemical (C25)
and physical (C110) properties. These standards can be purchased
directly from ASTM at www.astm.org.
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Q:
Do you have technical advice on how to design lime storage
and conveyance systems? What type of lime handling equipment
should I buy?
A: NLA’s
"Lime Handling, Application & Storage" publication includes
information on the handling and storage of lime, equipment
for application of lime, lime slaking and slurry handling,
and factors affecting the selection of lime. Contact your
lime supplier for more specific technical assistance and advice
on equipment vendors.
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Q:
How does the National Fire Protection Association (NFPA)
rate lime?
A: The NFPA has a 0 to 4 rating system for potential hazards
that may be encountered during fires and other emergency response
situations. NFPA classifies calcium oxide (quicklime) as a
serious health hazard (category 3) because of its potential
to cause irreversible injury to the eye. The NFPA classifies
quicklime as a non-flammable material (category 0), and slightly
reactive with water (category 1). More details appear in NPFA’s
Hazardous Chemicals Data Handbook (NFPA 49), see www.nfpa.org
. The NFPA Handbook does not include ratings for other forms
of lime or lime by-products, but by NFPA’s criteria, hydrated
lime should be a category 1 health hazard and category 0 for
both flammability and instability hazards.
For safety precautions, the MSDS for the specific product
should be reviewed.
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Q:
How much lime should I use to stabilize clay soils to generate
long-term strength gain?
A: A fact sheet on soil stabilization is available under
Technical
Information.
There is an ASTM test method to approximate the amount
of lime needed to stabilize soils, D 6276. (This procedure
is also called the Eades and Grim test.) The standard can
be purchased directly from ASTM, www.astm.org
. However, to be confident that a stabilized soil can provide
structural strength, more rigorous testing is required.
The National Lime Association has proposed a testing protocol
in a report entitled "Evaluation of Structural Properties
of Lime Stabilized Soils and Aggregates, Volume
3: Mixture Design and Testing Protocol for Lime Stabilized
Soils." March 2000. This report is available under Technical
Information.
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Q:
Can’t lime be used to dry up mud—for short-term soil modification
to expedite construction?
A: Yes, a fact sheet on using lime to dry up mud is available
under Technical
Information.
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Q:
How much lime should I use on my garden?
A: Hydrated lime can be used to raise the pH of acidic
soils. This is also referred to as soil "sweetening." Hydrated
lime is available from garden centres and should be applied
in the amounts and using the procedures recommended on the
packaging.
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